To disconnect WooCommerce from Facebook, follow these steps:
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Go to your WordPress dashboard and navigate to WooCommerce > Settings.
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Click on the Integration tab.
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Locate the Facebook for WooCommerce option and click on Manage.
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In the Facebook settings page, scroll down to the Remove Integration section.
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Click on Remove to disconnect your WooCommerce store from Facebook.
This will unlink your store from Facebook, removing any sync with Facebook Catalog, Facebook Ads, and other related features. If you want to reconnect later, you can follow the same process to link again.